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First, excitation with a spatially varying B1 causes flip-angle artifacts and second, spin locking with an inhomogeneous B1 results in non-uniform T1ρ contrast.
We investigate theoretically and experimentally the role of broadening due to heteronuclear dipolar coupling in spin-1 nuclear quadrupole resonance pulsed spin locking.
A multiple-pulse pulse sequence of the so-called "Pulsed Spin Locking" (PSL) type was used to acquire the data.
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The hex locked, fixed weight dumbbell or a spin locked dumbbell are good choices.
N R1ρ data have been measured at a MAS frequency of 39.5 kHz, and spin-lock rf field strengths of 2 15 kHz, that is, far from the n=1 rotary resonance condition (which is at 39.5 kHz).
In helical liquid on surface of topological insulator, due to the spin-momentum locking, spin-plasmon manifests itself as coupled charge- and spin-density waves.
Another often used approach, sometimes referred as on-resonance saturation, is chemical exchange spin lock (CESL), which employs a spin lock module similar to that used in T1-rho imaging [36 38].
In the 2D-1H-NMR theSY the receptor NMR signal was filtered during the 80 ms spin lock, resulting in a cleaner analysis of chemical shift perturbation.
Correlation spectroscopy (COSY) [54], total correlation spectroscopy (TOCSY), using the MLEV-17 pulse scheme for the spin lock [55], and nuclear Overhauser effect spectroscopy [56] experiments were acquired under identical conditions for all samples, using gradients for water saturation.
In the following series, different SL pulse durations (time of spin lock, TSL) are applied.
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