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No changes were observed in the Raman spectra until the strain rate was larger than the critical value for the coil-stretch transition.
To determine the maximum solubility of the suspension, the supernatant solution of the saturated suspension was diluted several times for the measurement of UV Vis spectra until the absorbance fitting in the range of calibration line.
Fig. 7 FTIR spectra for TNTs based on different NaOH concentrations Fig. 8 FTIR spectra until complete formation of TNTs: a OH group (3600 3200 cm−1), b Ti-OH group (1500 1100 cm−1) and c Ti-O group (700 400 cm−1).
Features assigned to the SERS nanoprobes' Raman reporter (4-MBA) dominate the spectra, until the concentration drops below ∼10 nM and the area of aggregation becomes smaller than the laser spot size of 3.1 μm.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com