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Specific rotations of all compounds showed that only one optical isomer was formed.
These absolute configurations were further confirmed using experimental and theoretical specific rotations.
Specific rotations were recorded on an Optical Activity AA-10 Automatic polarimeter with a path length of 1 dm.
The specific rotations of these chiral polyimides ranged from −48.5° to +73.0° depending on the structures of the aromatic dianhydrides.
Polysaccharide was dissolved in 1 N NaOH at a concentration of 10 mg/ml and specific rotations and optical rotations were determined using a Perkin-Elmer Polarimeter.
The spectral data of eusynstyelamide A (226) was similar to previously reported compound eusynstyelamide from a Fijian Ascidian E. misakiensis [129], remarkably, the compound showed opposed specific rotations.
Similar(41)
A substance with a positive specific rotation is described as dextrorotatory and denoted by the prefix d or ; one with a negative specific rotation is levorotatory, designated by the prefix l or.
Because the specific rotation depends upon the temperature and upon the wavelength of the light, these quantities also must be specified.
Although the specific rotation (a function of the concentration of a protein solution and the distance the light travels in it) of most L-amino acids varies from −30° tο +30°, the amino acid cystine has a specific rotation of approximately −300°.
The intensity of optical activity is expressed in terms of a quantity, called specific rotation, defined by an equation that relates the angle through which the plane is rotated, the length of the light path through the sample, and the density of the sample (or its concentration if it is present in a solution).
The specific rotation of o-HOP was -43.2°.
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