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In the presence of hydrogen concentrations between 1200 and 3400 appm, the high special fraction microstructure showed almost double the tensile ductility; also, the proportion of intergranular fracture was significantly lower and the Jc fracture toughness values were some 20 30% higher in comparison with the low special fraction microstructure.
A special fraction A in TBIR-40 was random copolymer containing a few TPI and trans-1,4-polybutadiene (TPB) blocks, and both TPI and TPB blocks had the ability to crystallize.
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Grain boundary engineering, which increases the special boundary fraction, may improve microstructural stability during annealing.
The results presented here show that nanocrystalline plasticity leads to an increase in special boundary fraction and disruption of two-dimensional boundary connectivity, with the most dramatic evolution occurring in the smallest grain sizes.
We find that multiple cycles of grain boundary engineering result in a material that resists abnormal grain growth better than other processing routes despite similarities in special boundary fraction, grain size, and general boundary connectivity among as-processed materials.
By thermomechanically processing the alloys to create specimens with largely different special boundary fractions, it was possible to isolate the effects of the grain boundary structure on the intergranular stress corrosion cracking behavior.
Furthermore, quantitative assessment of the boundary network topology shows that the special grain boundary fraction is a poor predictor of network topology, but that the higher-order correlation derived from triple junction distributions can successfully describe the length scales of random boundary clusters.
While all this evidence indicates that the egalitarian outcome has something special for a substantial fraction of subjects, it does not tell us anything about the exact fraction of subjects for whom this is the case.
The fraction of special boundaries reached 72% and the random boundary network was significantly dispersive.
Alloy 600 with fraction of special boundaries above 85% showed only uniform corrosion.
Connectivity of boundary types is more important than the absolute fraction of special boundaries.
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