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A hollow structure which is another effective strategy to improve the cycling stability could provide extra free space for alleviating the structural strain and accommodating the large volume variation associated with repeated Li+ insertion/extraction processes.
The polar MnO2 hollow spheres can not only provide enough inner space for alleviating the volume expansion for sulfur, but also effectively moderate the dissolution of polysulfides by synergistic effect of structural restriction and chemical adsorption.
The abundant pores inside the FePx matrix can store sufficient electrolyte for fast ion transfer, as well as provide enough space for alleviating the volume change during charge/discharge process.
The improved electrochemical performance in CNT@TiO2 nanohybrids can be attributed to the following factors: above all, the TiO2 nanoparticles were uniformly decorated on the surface of one-dimensional CNTs, which offered excellent flexibility and enough space for alleviating the effects of electrode degradation and volume change upon cycling.
As usual, one effective way to mitigate the problem is to fabricate a hollow structure, as a hollow interior could provide extra free space for alleviating the structural strain and accommodating the large volume variation associated with repeated Li+ ion insertion/extraction processes, giving rise to improved cycling stability.
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