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Faux solutions: mechanism vs. context.
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The observed hardening is attributed to the solid solution mechanism.
The principal solution mechanism is ZrO2 + 4NaOH = Na4ZrO4 + 2H2O with ∆H ~ 200 kJ/mol.
The principal solution mechanism is 2ZrO2 + 2NaOH + 2SiO2 = Na2Zr2Si2O9 + H2O with ∆H ~ 40 kJ/mol.
That approach limits the interpretation of the solution mechanism of Zr4+ in fluids because the presence of SiO2 in those experiments restricts identification of effects of individual components on Zr4+ solution mechanisms.
In particular, how chemical composition of melts affects water solubility and solution mechanism is not well understood.
However, the water solution mechanism for the LS4 glass is best described by the combination of Eqs.
Furthermore, the solution mechanism of reduced nitrogen as NH-complexes resembles that of dissolved H2O (Mysen et al. 2014).
Overall, the proposed solution mechanism improves existing results from the literature for the considered kind of problem.
Present data indicate that Eq. (2) alone cannot explain the solution mechanism of water in silicate glasses containing small alkali metals, such as Li and Na.
Nguyen and Bonnet [21, 22] introduce a solution mechanism to solve the issue of load balancing in the PMIPv6 by considering the IP multicast session.
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