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For example, in copper cementation iron replaces copper ions in solution, solid particles of copper precipitating while iron goes into solution.
Gas (hydrogen) – liquid (organic solution, reactant and products)–liquid (alkaline aqueous solution) – solid (catalyst) four phases existed in a batch reactor.
Three representative binary eutectic alloys Ag 39.9 at.%Cu, Ni 19.6 at.%P and Pd 16.0 at.%P – their eutectic products are solid solution solid solution, solid solution stoichiometric intermetallic compound and stoichiometric intermetallic compound stoichiometric intermetallic compound, respectively, were solidified at large undercooling.
A thermodynamic analysis of phase equilibria in the Cu Al–O system shows that a five-phase equilibrium exists among solid copper with oxygen in solution, liquid copper with oxygen in solution, solid CaAlO2, Al2O3 and oxygen gas at the invariant state T=1348 K, pO2=5.6×10−7 atm (0.055 Pa).
Figure 7 29 Si MAS NMR of batch reactions at a solution:solid of 5 1.
Figure 6 29 Si MAS NMR of batch reactions at a solution:solid ratio of 10 1.
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Compared to that in solution, solid-state UV vis absorption spectrum of the polymer showed a strong bathochromic shift, indicating more efficient π-stacking and stronger intermolecular interactions.
Before we start to discuss analytical methods and results, we will briefly lay out the most important concepts used to describe aqueous solution solid-solution systems.
Tracer studies indicate that the +3 oxidation state exists in solid compounds and in aqueous solution as the Es3+ ion; there is also some evidence for a +2 state in some nonaqueous solutions, solid solutions, and gaseous species.
After removal of supernatant solutions, solid phases were washed two times with deionized water, dried under N2, and split for analyses.
At a critical θp, the two solutions (solid lines, dashed lines) coalesce and disappear at a saddle-node bifurcation (SNB) (Strogatz, 1994).
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