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This dependence leads directly to a backstress in the underlying flow rule, and allows us to model the rapid strain-hardening response after the initial yield-drop in monotonic deformations, as well as the Bauschinger-type reverse-yielding phenomena typically observed in amorphous polymeric solids upon unloading after large plastic deformations.
Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide.
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A club attempting to go a long way in a short time need a firm identity, something solid upon which to build.
What these creatures do is something no laboratory has been able to achieve: control the chemistry so exquisitely that the silk, which is a liquid inside the organism, becomes a solid upon leaving it.
This material had an appropriate viscosity of 0.18 Pa s at 25°C and was converted to a soft solid upon an arbitrary timing of photoirradiation.
After 10 min, the product was purified by semi-preparative HPLC using a gradient of 0%to40%0% MeCN in 6 min and was obtained as a white solid upon lyophilization (13.8 mg, 2.8 μmol, 89%).
The product was cleaved from the solid support and deprotected using a mixture of TFA (trifluoroacetic acid)/TIS (triisopropylsilane)/H2O (95:2.5 2.5) for 45 min. The product was purified by semi-preparative HPLC using a gradient of 0%to3030% MeCN in 6 min and was obtained as a white solid upon lyophilization (49.8 mg, 31.6 μmol, 32%).
After plenty of mid-production and pre-opening hoopla, "Gone Girl's" box office was undoubtedly solid upon opening this weekend.
Reaction of GeCl4 with [EMIM]Cl gave a white solid upon removal of all volatiles.
The solvent was removed under reduced pressure and the crude product redissolved in CH2Cl2 followed by precipitation of an orange solid upon addition of hexane.
NP configurations corresponding to N = 55 are shown in Figure 2 b, where we see an odd form of melting in which the NP transforms from a crystal having icosahedral symmetry solid to a disordered liquid during heating and freezes into an icosahedral symmetry solid upon cooling.
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