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For the evaluation and design of crystallisation processes solubility data of solids in mixtures of a solvent and carbon dioxide is crucial.
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In this study, PR+COSMOSAC EOS is applied to predict the solubility of solid solutes in mixtures of ScCO2 + organic solvents (e.g., acetone and ethanol).
While the vapour liquid equilibrium data of solvents and CO2 are usually available, the solubility of solids in a mixture of a common solvent and CO2 are not.
Additionally, ESR experiments were carried out to study this system in bulk, in solid phase mixtures of donor and acceptor, and at a donor acceptor solid liquid interface.
Subsequent photoluminescence (PL) quenching and light-induced electron spin resonance (ESR) experiments were carried out to study this system in bulk, in solid phase mixtures of donor and acceptor, and at a donor acceptor solid liquid interface.
The template was extracted by stirring the solid in a mixture of 100 g of acetone and 10 g of 2 M HCl.
Then the solid material was dissolved in methanol and subsequently precipitated in mixture of acetone/ethanol solution with a ratio of 4/1.
A linear relationship between probe signal and fraction distribution of solids in binary mixtures was found.
The solubility of 23 solid solutes in different mixtures of ScCO2 + organic solvents with pressures up to 40 MPa and temperatures ranging from 298.15 K to 353.15 K are used to evaluate the accuracy of PR+COSMOSAC EOS.
RM was added to enzymatically hydrolyzed whole slurry (20% total solids) or to mixture of solids and enzyme in the case of SSF.
Solids orientation is influenced by the principal orienting factor (shear flow) and the randomizing factor (orientations of other solids in the mixture).
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