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In order to establish an empirical equation between pore size and solid-liquid transition temperature, a series of mesoporous SBA-15 model samples was investigated.
Even though the melting point and latent heat of fusion are dependent upon the particle size, the alloying effect on the solid-liquid transition temperature can still be discussed using the classical thermodynamic equation given below [44].
Accordingly, the solid-liquid transition temperature in the gold-silver binary system decreases with an increasing silver fraction, and thus, it can be inferred that the coalescence temperature follows the same tendency due to alloying, as marked in the lower left circle (at the low silver side) in Figure 11a.
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Their characteristics, and more specifically, the solid to liquid phase transition temperature and enthalpy, are usually obtained through DSC.
They attribute this phenomenon to a strong influence of solid-liquid phase transition in the capping molecules on the size-dependent "luminescence temperature antiquenching" [13, 14].
Inthe context of solid-liquid phase transitions, v and u represent theabsolute temperature and the order parameter which indicates the physical situation ofthe system, respectively.
Solid to solid and solid to liquid transitions were recognized during HP treatment.
Thus, the temperature in the EPCM remains constant at the selected melting temperature until the solid to liquid transition is complete (provided heat transfer within the EPCM is rapid).
In this case, the effect of the solid surface was an increased transition temperature and a broadening of the transition.
When cooling amorphous food materials, the very steep dependency on temperature gives rise to a moderately well-defined transition from liquid behavior to solid behavior at the so-called glass transition temperature, Tg.
The solid lines indicate the determination of the transition temperature as described in the text.
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