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The particle sizes of the materials were also investigated.
The surface area, pore volumes and pore sizes of the materials were related to their maximum hydrogen excess and total hydrogen capacities.
The addition of F− dramatically improves the structural periodicity, but enlarges the pore sizes of the materials at the same time.
The calculated average crystallite sizes of the materials Fe3O4/PVP (1 g), Fe3O4/PVP (2 g) and Fe3O4/PVP (3 g) were found to be 35, 32 and 30 nm, respectively.
Using XRD software that takes instrumental peak broadening into account (Feng et al. 2003), the most intense peaks were used as references (2θ = 29.4 and 16.0° for BC and Fe2O3 BC, respectively) to calculate values of crystal sizes of the materials.
There are three different methods to calculate the pore sizes of the materials: (a) the BJH method; (b) geometrical considerations of an infinite hexagonal array of cylindrical pores, expressed by averaged pore diameter (APD) (eqs 1), 1and (c) the model of simple cylindrical pores using the BET surface area (eqs 2), 2 Figure 2c shows the small-angle XRD patterns of MSN-1 and MSN-2.
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After phospholipids addition, BET measurement with BJH method was achieved to measure the surface areas and pore-sizes of the materials.
The most limiting factor is the size of the materials.
However, the pore size of the materials was increased by the silicification process.
The coherent scattering block size of the materials obtained is decreased with increase of milling time.
Particle rearrangement dominated the initial compression profiles due to the small particle size of the materials.
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