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Two samples containing a common analyte, acetonitrile, were used to demonstrate signal cancellation in a difference spectrum collected with a single pulse experiment.
A number of 16 transients with 65,536 data points each were collected to ensure a signal to noise ratio of >300 for the relevant peaks, with a standard single pulse experiment without decoupling.
Two types of one-dimensional H spectra were recorded, a single pulse experiment with water suppression and a spin-echo experiment (CPMG) for suppression of broad signals from macromolecules.
For qualitative H NMR measurements, a standard single pulse experiment with 16 scans, a flip angle of 30°, and a relaxation delay (D1) of 2 s were utilized and the spectral width was set to 22 ppm with 65,536 data points, and for P NMR, a single-pulse sequence was used with power-gated decoupling and a flip angle of 30°.
Similar(55)
A series of single pulse experiments is used to construct phase transition curves, from which limit point (Arnold tongues) and period-doubling bifurcation boundaries can be constructed.
The adsorption and oxidation of CO on a 1.0% Ag/MnOx catalyst between 393 and 493 K were studied by means of single pulse experiments in a TAP reactor.
This result was confirmed with single pulse experiments.
A standard single-pulse experiment was used to acquire the 1H spectrum using a 6000 Hz spectral window, 30° pulse width, an acquisition time of 3.0 s, with 64 K complex data points.
Measurements were performed at 202.5 MHz, using a single-pulse experiment with a 12.0 µs pulse, 1.2 s relaxation delay time and broadband proton decoupling.
A single-pulse experiment (zgpr; Bruker) was performed for all samples.
No relevant influence of the chromophore density was found for the threshold fluence of laser ablation (∼25 mJ/cm2) of the four polymers for single-pulse experiments.
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