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She strips back the extruded wire's polymer coating and reveals its lustrous silver core.
The growth of the metallic silver core was suppressed by the addition of dithiophosphates.
Then, a selective etching process of the silver core was performed in a 7.5 M HNO3 solution.
Washing of Ag@C nanoparticles with nitric or hydrochloric acid solutions also leads to dissolution of encapsulated silver core and formation of hollow carbon nanocapsules.
Single Pulse Column Experiment (SPCE) results show both the PVP polymer and the silver core controlled AgNP deposition while the effect of the PVP was dominant.
Such process is what we observed for both systems previously formed silver core with a new gold shell and vice versa (Fig. 1b).
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With the silver cores forming, the ligands (dithiophosphate) coated the surface of the silver cores quickly and separated from the reaction system.
This result recommends that the silver cores in the PPy silver nanocomposites are in FCC phase.
According to TEM, the silver cores are mainly covered by small gold particles.
The silver nanodiscs strongly absorb visible light with minimal scattering, whereas the silica shell maintains the shape and absorption spectrum of the silver cores.
The 3D-NPG nanostructures are formed by replicating the silver nanoislands, after a selective etching of the silver cores (Figure 1c).
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Justyna Jupowicz-Kozak
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