The peaks at approximately 93 and 45 ppm in GA13 and 101 and 29 ppm in GA27 are tentatively assigned to environments such as Fe2AlOD and FeAl2OD, respectively, while the higher frequency resonances are assigned to environments such as Fe3OD, the higher frequency shoulders originating from hydrogen bonding to an O2– anion coordinated to Al3+.
This spectrum is characteristic for an anionic semiquinone radical representing the interaction of the unpaired electron with two N nitrogen atoms at position 5 and 10 in FAD (with the shoulders originating from the Azz value of the N coupling) [29].
Hence, the peak shift and the shoulder originated from the large overpotential for Fe deposition during the on-time pulse.
In the front portion of the shoulder, originating from the scapula, the muscles involved are the subscapularis muscle and the biceps muscles (Figure 3).
It has been estimated that approximately 44-80% of all shoulder complaints originate from these anomalies of structures in the subacromial space [ 9][ 10].
Participants found it difficult to specify anatomical sites of MSDs if they had referred pain, for example if they had shoulder pain originating from their neck; "I think I answered more things about the neck, when I thought back I thought, oh no that's really down your shoulder" (P5).
In short, the song has nothing to do with the sinuous, shoulder-dipping dance move that originated in Harlem.
These peaks are located above a shoulder which can originate from Si-O and Si-OH phonons [23, 24].
As shown in Figure 7, the major absorption peak of MB aqueous solution appeared at ca. 664 nm originated from MB monomer, and the shoulder peak at ca. 615 nm originated from the dimer of MB [39, 40].
The shoulder located at 3.54 eV has been reported to be originated by the n-π* transitions [28].
