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From the figure, three major shoulder bands were observed at 300, 350, and 430 nm ranges.
The UV vis absorption maxima of hyperbranched polymers are similar to that of P3HT in film state, while their absorption shoulder bands are stronger than that of P3HT, indicating stronger interchain interaction and shorter distance between backbones by the introduction of bridge architecture.
High absorbance values from water-stretching bands are seen around the sample boundaries (Fig. 9b) due to the structural hydroxyl of zoisite with representative frequencies at 3185 cm−1 and shoulder bands at 3275 and 2145 cm−1 (Langer and Lattard 1980).
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Angela Missoni's sari-sarong outfits were not quite plain, with their diagonal shoulder band and a silk kick-pleat in the pencil skirts, but they were very flattering.
shoulder band.
The electronic absorption spectrum of Co-DPP-Co exhibited absorption in Vis-NIR region with shoulder band in longer wavelength region.
When the urea/metal ratio is increased to 2 in the preparation, the shoulder band at 870 cm−1 decreases further.
More importantly, the Lewis acidity strength was also enhanced with the appearance of a shoulder band at 1,450 cm−1.
In addition, the associated shoulder band at 1,453 and 1,597 cm−1 was assigned to strong Lewis acidic sites [21, 22].
Besides these three bands, one weak shoulder band emerged at 960 cm-1 that was usually attributed to the Si-OH stretching vibration.
In addition, the associated shoulder band at higher wave number of 1,450 cm−1 was assigned to the LAS with stronger acidity strength [20, 21].
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