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Electron irradiation led to a negative shift of the reduction peaks and a positive shift of the oxidation peak.
Electrochemical studies exhibit anodic shift of the reduction potentials of the CoIII center in the presence of Na+ thereby indicating complexation of these ions to the crown moiety.
The influence of structural parameters on the stability of the compounds was discussed considering the shift of the reduction potential of the complexes.
The best electrocatalytic activity was obtained on Ag which showed a shift of the reduction peak potential of 771 mV with respect to GC, the most inert material.
The negative shift of the reduction peak can be attributed to exchange of electrons between the silicon and diazonium molecules that are reduced on the already grafted molecules allowing the formation of a multilayer structure.
Compared to Al electrode, a cathodic shift of the reduction potential of the Th4+ is observed on the Al film electrode which is not conducive for the potentiostatic extraction of thorium.
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Compared to MoS2, downward shifts of the reduction temperatures were observed in TPR for Co(Ni)–Mo S sulfides which suggested a decrease in metal sulfur bond strength.
This finding correlates well with the H2-TPR and CO-TPR results, which demonstrated the shifting of the reduction temperature towards lower temperature ranges than bare CZ support with the incorporation of Ni in Ni/CZ-AE catalyst.
The consequent shifting of the reduction towards slight excess tensions in comparison with the electrode free of adsorbed substance, the degree of actual coverage, and the type of adsorption isotherm give rise to the conclusion that the iodate molecule is split on a sulphur-covered platinum electrode in a predetermined heterogeneous-catalytic process.
The incorporation of MW-CNTs in the film leads to a significant decrease in the hydrogen peroxide produced during the oxygen reduction reaction (ORR) and a significant positive shift of the oxygen reduction potential.
60-10-1 exhibited the largest positive shift of the first reduction potential vs C600/–, +0.57 V, but a few compounds 60-6-2 60-6-2 60-6-2-12-3) exhibited a negative shift of the first reduction potential (the most negative value was for 60-12-1).
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