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This proves the anodic shift of the potential and the stabilization of the oxide film.
Gradual shift of the potential toward more negative values resulted in the change of the morphology of the layers from crystalline via dendritic to porous.
Presence of methanol retarded the formation of the oxide layer of Pd, giving rise to an anodic shift of the potential.
The step dipole moment is determined from the shift of the potential of zero charge (pzc) as a function of the surface step density.
In the polymer coated area the conversion film leads to a cathodic shift of the potential as measured by means of the SKP.
This property, along with the positive shift of the potential for ORR at the MOF-modified electrode compared with that at the bare GC electrode, demonstrates the electrocatalytic activity of the Cu-bipy-BTC MOF towards ORR.
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The increased negative shift of the potentials indicates the increased effectiveness of the cathodic protection of photoanodes.
However, for other POMs such as [PW12O40]3−, [H4AsW18O62]7−, [P2W15Mo2VIVO62]7−, α1-[P2W17O61FeIII]7−, α2-[P2W17VO62]8− and [P8W48O184]40−, the microenvironment effect results only in a shift of the potentials towards the negative values.
Comparison of the activation and inactivation curves obtained from the same cells before and after application of 5 mM TEA did not reveal any significant shift of the potentials of half-maximal activation or inactivation (n = 7, p = 0.83 and p = 0.89, respectively, paired t test).
This behaviour was associated to the strong oxidation of the positive electrode caused by the progressive shift of the working potential towards very positive potential values during cycling.
The cyclic polarization curves showed that sulphate addition to the chloride solution produced a poor reproducible shift of the breakdown potential to more positive potentials.
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