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Another consequence of amide linkage is the observation of red shift in spectra.
Moreover, a careful analysis of the -CH2 symmetric and anti-symmetric stretching modes revealed a slight downward shift in spectra recorded inside steatotic vesicles when compared to spectra recorded outside, suggesting a different lipid environment inside the steatotic vesicles.
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It can be found that introducing electron withdrawing group (CF3) on benzene moiety can stabilize HOMO level, thus leading to wider HOMO-LUMO gap and blue shift in spectrum.
Because transmission electron microscopy (TEM) showed that antibody-free AuNPs were aggregated in cells and the antibody-conjugated AuNPs were singular, Curry et al. noted that the aggregation of antibody-free AuNPs in cells contributed to a red-shift in spectra [26].
These previous studies led us to hypothesize that increased serum concentrations and a move from in vitro to in vivo serum levels may lead to smaller NP agglomerates within cells and smaller shifts in spectra.
Dramatic changes in heart beating (as seen in Additional file 2: Movie S2 showing the effect by Clofilium when compared to no effect of DMSO control in Additional file 3: Movie S3) and shifts in spectra were clearly observed with clofilium, a potent hERG channel inhibitor.
Thus, target molecules could be connected to peptides on nanoCA and then elicit resonance wavelength shifts in detections for TNT and DNT, while 3-NT and TNP had no conjunction with the peptide and did not generate shifts in spectrum.
The expansion of the π-system of the ligand induces the bathochromic shift in absorption spectra.
Upon boron doping, we observe a characteristic red shift in photoluminescence spectra.
This peaks' shift in PL spectra is induced by Si-Ge interdiffusion and quantum confinement effect.
The coincidence data set stringent constraints on theoretical models that were introduced to interpret the peak shift in inclusive spectra.
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