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In particular, the KAHR model was used to predict volumetric relaxation time-temperature shift factors that are directly compared to measured time-temperature shift factors in shear.
The shift rates and the temperature shift factors can be then obtained from the model parameters.
The time-temperature shift factors were computed using an automated curve shifting programme.
The Williams-Landel-Ferry equation was fitted to the time shift factors.
The overall shift factors correlate linearly with the maleic anhydride content of the rubber phase.
The modified shift factors are obtained from the effective relaxation times and the material constant (Cτ).
Fig. 8 shows two examples of test images that require small shift factors.
Certain important parameters, such as the shift factors, are identified by theory and experiments.
Finally, a set of shift factors were derived between the full-scale, OT, and CDCT tests.
The shift factors thus derived are fitted against the experimental temperatures using the Williams, Landel and Ferry equation.
The results are then used to obtain the shift factors and develop both Williams-Landel-Ferry (WLF) and Arrhenius models.
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