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The hetero nitrogen substitution of HBX resulted in the red shift emission spectra, which implies that the lone pair of electron in the substituted nitrogen has the effect on the π-conjugated system.
The red shift emission was possibly due to the fact that in Eu2+ silicate the Madelung potential of the negative anions around Eu2+ is felt less by the 5d electron, leading to a lowering of energy [17].
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Of course, CO2 emissions aren't saved if we just shift emissions from tailpipes to power plants.
This compound also exhibits high thermal stability and blue-shift emission, and can be explored for potential blue luminescent materials.
Results suggested that the norfloxacin substituted naphthalimide derivatives indicate red-shift emission maxima when compared to 4-bromo 1,8-naphthalic anhydride.
The two probes not only showed >100 nm blue-shift emission with two well-resolved bands upon addition of HSO3−/SO32−, but also displayed rapid response, high selectivity and sensitivity for monitoring and quantifying HSO3−/SO32− over other species in living cells.
Upon Zn II) titration, a broad red shifted emission occurred, centred at 468 nm.
The luminescent behaviour of the complex and the ligand were also investigated and the complex shows blue shifted emission.
Pyridine containing polyamide 41 exhibited slightly blue shifted absorption band relative to its phenylene analogue 36 while its emission showed a red shifted emission peak at 420 nm.
Exciplex usually leads to the red shifted emission and broadened spectrum relative to the emissions of the individual acceptor or donor [7 10].
In the presence of Cd II), a similar red shifted emission was also observed, however, this time centred at 506 nm.
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