Sentence examples for shift deviation from inspiring English sources
The phase shift deviation is less than 2.1°.
Among others, ranking of the constitutional assignments by chemical shift deviation and/or substructural elements have been tested [25, 26] integrated to COCON runs.
Figure 13 Solution to the problem for boletunone A. The revised structure, A, was unambiguously distinguished as the best structure by the average chemical shift deviation, while structure awas not generated at all because the presence of nonstandard correlations was not allowed.
The largest chemical shift deviation was observed with Phe20 (8 Hz).
A large chemical shift deviation was also observed with Ala21 and Glu22, 5 and 3 Hz, respectively.
To characterize the structural/dynamic property of CfAFP−501, especially its potential change with temperature, a combined analysis of the temperature gradient of amide proton chemical shift (Δδ/ΔT) with chemical shift deviation (CSD) [20] was performed.
The values of R2 calculated for structures B and b are equal to 0.999 and 0.995 while the maximum chemical shift deviations are 3 ppm (B) and 9 ppm (b).
The agreement with the NMR amide proton chemical shift deviations is remarkable.
Non-terminal residues that were unaffected by the addition of NQTrp showed mostly chemical shift deviations of less than 1 Hz.
2) Comparison of the chemical shift deviations reveals that while in V22-SH3 the second helical region is similarly populated as in the wild-type SH3 at pH 2.0, the first helical region is largely unformed.
Very interestingly, here as judged from the chemical shift deviations, it seems that in V22-SH3, the non-native helical conformation is highly populated over the secondary region but no significant secondary structure preference is populated over the first region.
