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If genuine needs turn out to be smaller than expected, flexible funding arrangements could allow donors to shift contributions between budgeting years.
This approach has been successfully applied to a range of systems, and novel modifications to it have even allowed the shift contributions from individual structurally distinct bond pathways to be assessed.
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The increase in shift upon Al substitution for the H-bonded pathways indicates that their hyperfine shift contribution is negative, and hence that these types of pathways contribute a negative unpaired electron density at the H nucleus.
Thus, taking these issues into account makes the isolation of the phase shift contribution of (V_{text {E}}) and therefore electronic characterization of CIGS by EH challenging.
The pathways have similar geometry as for the 1NN pair (94.8 and 103° bond angles, only one oxygen protonated) that has a positive shift contribution, so the negative shift contribution is likely related to the protonation of the oxygen atoms in the bond pathways (or possibly to incremental changes in the long-range structure that come about when Al substitutes into the 2NN position).
Since in PpcA the non-haem aromatic rings, (Phe and Phe) are in distant regions in relation to Asn amide protons, the observed chemical shift of these protons can only be explained by the ring-current chemical shift contribution from haem III.
Their study shows that the electrode curvature effect on the total interfacial capacitance can be a strong function of applied voltage, which we attribute to the shifting contributions of CQ and CD.
Ms. Hardt cited a shift in contributions to other charities after the Sept. 11 terror attack.
The industry's shift in contributions toward Democratic candidates mirrors wider trends among donors, but the donations from this sector are particularly notable because of the party's focus on overhauling the health care system.
If the IRS were to follow up with additional rules limiting the amount of permissible political activity or requiring donor disclosure — as we think it should — donors are likely to shift their contributions to trade associations, where these IRS rules would not apply.
This is not a bad idea: such a fund could lead to a shift from contributions linked to pay, which drive up labour costs (and unemployment).Yet the fund has turned into a monster, whose only purpose is to bridge the policy gap between the parties.
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