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Neutral-π radical based open shell molecules foster new potential in light emitting diodes because of their theoretical near-equity quantum efficiencies.
Fast chemical reactions between closed shell molecules.
This is a most unusual finding for a reaction involving two closed shell molecules.
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In this study, we report organic light emitting diodes (OLEDs) based on a novel open shell molecule (2,4,6-trichlorophenyl 2,4,6-trichlorophenyllectrolumethylenTTMaser.
Here, we develop a blend of open-shell small molecules and closed-shell, conjugated polymers in order to evaluate how the chemical composition of the distinct open-shell, charge-neutral molecular dopants impacts the thermoelectric performance of a common hole-transporting (p-type) polymer semiconductor, poly 3-hexylthiophene) (poly 3-hexylthiophene
However, the three times denser 1 × 1 phase (coverage x = 3), with all hollow sites occupied, does not form because the distance between adsorbate molecules would be 4.26 Å/ 3 = 2.46 Å, significantly less than the size of any closed-shell atom or molecule.
The specific short-range interactions of a metal cation in water arise from reorientation of the first shell water molecules.
We report for the first time solution processed open shell organic molecules for light emitting diode applications.
We describe the behavior of the local molecular structure under increasing temperatures and the effect of peptide interactions with nearest hydration shell water molecules on peptide mobility and propensity to exhibit structural transitions.
Moreover, to enter the channel, the G0-G4 PAMAM dendrimers are expected to reorganize their solvation structure, losing all or almost all shell water molecules and counterions.
Organic chemists had to start with the design and construction of more-or-less stable open-shell organic molecules.
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