Exact(5)
Subsequently, the holes transferred to MoO3 hop to the Ag electrode through the shallow defect states generated by the oxygen vacancies [97].
Both donors (titanium interstitials and oxygen vacancies) and acceptors (titanium vacancies) are predicted to have shallow defect transition levels in the electronic-structure calculations.
As well the onset of both the absorption spectra at 0.68 eV, we attribute to the transition from EL2 defect center to the conduction band considering the possible way through the shallow defect levels [24 27, 29].
Generally, the hole transport in nanostructured MoO3 layer occurs via the shallow defect states present in its band gap formed as a result of oxygen vacancies [93, 94, 95].
The feature at 1.11 eV can be caused by the transitions between band and shallow defect levels in the MB, and the one at 1.17 eV can be related to the WL absorption, which corresponds to the WL PL peak at RT.
Similar(55)
The density of the shallow defects was found to increase with increasing concentration of incorporated nitrogen.
In the literature, many examples of CdS NCs in which shallow defects play an important role are reported [28, 29].
Capacitive imaging technique can be used as complementary to UT for imaging shallow defects in composite materials at depths where UT has insufficient time domain resolution.
In our case, the intensity of emission from shallow defects is very low with respect to the emission band edge, indicating a good optical quality of synthesized CdS NCs. Figure 4 PL spectra of CdS NCs.
Besides, the Raman results support the PL redshift of the MWs due to radiative recombination through shallow defects induced by humidity (explained previously in the "Photoluminescence Evolution of MAPbI3 Microwires Under Humidity" section).
As in LRS, electrons conduct through metal filaments from the top electrode to the bottom electrode, and in HRS, electrons conduct through shallow defects between the tip of ruptured filament and the bottom TiN electrode.
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