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Tetrachloroethylene was selected as extraction solvent.
Ultrasound assisted extraction was selected as extraction method.
In the proposed method, 4- 2-pyridylazo) resorcinol (PAR) is used as a chelating agent, and chloroform and ethanol are selected as extraction and dispersive solvent.
The variables of interest in the HLLME-FA were selected as extraction and homogeneous solvent volumes, ionic strength and extraction time.
In the proposed method, dithizone was used as a chelating agent, and carbon tetrachloride and acetonitrile were selected as extraction and dispersive solvents.
Divinylbenzene/carboxen/polydimethylsiloxane was selected as extraction fibre and was used to evaluate the influence of exposure time, extraction temperature and sample volume/total volume ratio (Vs/Vt) by means of a central composite design (CCD).
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Compared with dichloromethane and petroleum ether (30 60 °C), ethyl ether was found to be most effective in the extraction of EO and was selected as the extraction agent.
As a result, ethyl acetate gave the highest extraction efficiency, and ethyl acetate was selected as an extraction solvent of the analyte derivatives from samples.
The obtained results showed that chloroform has the highest extraction efficiency for the silver ions; thus, chloroform was selected as the extraction solvent for further experiments, Table S1 (in Additional file 1).
Methanol, 80% methanol, 60% methanol and 40% methanol were used as extraction solvents (Additional file 1: Table S1), among which 80% methanol showed the best extraction efficiency for the six anthraquinone glycosides and was thus selected as the extraction solvent.
For the PLE procedure, methanol was selected as the extraction solvent.
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