Sentence examples for second equivalent of the from inspiring English sources

This indicates that the formation of the oxaphosphole is faster than the nucleophilic attack of intermediate D C on a second equivalent of the ketone.

If the sulfonium intermediate maintains a sufficiently unhindered α-position, then nucleophilic attack by a second equivalent of the thiol would generate the BTE product and one equivalent of the thioether derived from the incident thiol (Fig. 6c).

Accordingly, gold(i) coordinates with the alkyne making the proton more acidic, leading to an alkynyl gold(i) complex that reacts with a second equivalent of the catalyst to form 97. Nucleophilic attack of the allene generates allyl stabilized carbocation 98 in the rate-determining step, which is followed by an intramolecular 1,5-hydrogen shift leading to 96 through diaurated species 99.

However, the insertion of a second equivalent of AlL into the opposing P P bond of the P4 tetrahedron occurs rapidly yielding the two-fold insertion product 4 (Fig. 2).

The reduced flavin subsequently reduces the second equivalent of enone 1a, which resembles the oxidative half-reaction, and closes the catalytic cycle.

This species forms via the transfer of a [Ph2P]+ moiety from a second equivalent of 36f + to the reactive intermediate 60f +.

Addition of a second equivalent of SAM and reductant (dithionite) to the sample of the purified intermediate is associated with significant Mössbauer spectroscopic changes.

In this reaction, an iminium cation is formed as an intermediate which is reduced by the second equivalent of N-methylformamide.

This reacts with the second equivalent of Ph2PCl yielding 8 +.

The reaction of 32h + with the first equivalent of L yields the experimentally verified species 69 +.

We therefore propose that the first equivalent of BH4 that binds to nNOS is able to create one tight-binding site by a process that involves redox chemistry.