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However, we decided to examine the scope of this cycloaddition.
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As a result of this cycloaddition, the bottom C17 C18 bond gains double bond character (1.340 Å).
Further work on the application of this cycloaddition in synthesis is underway.
(24) Given the particularly promising nature of this cycloaddition reaction, the optimization of this synthesis was an important task.
The nontoxic, copper free nature has raised this strain-promoted azide alkyne cycloaddition (SPAAC) as one of the top choices of bioorthogonal reactions, in addition to the fact that none of the reactive functionalities of this cycloaddition reaction are found in or reactive toward biological systems.
Having established reaction conditions for the mild cycloaddition of triazine 1 a with alkynyltrifluoroborates, we set out to explore the scope of this chemistry for the preparation of bipyridyldifluoroboranes, our results are shown in Table 2.
Scope of this part.
Outside scope of this codification.
§ 715.1 Scope of this part.
However this is beyond the scope of this paper.
The scope of this paper is twofold.
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