Sentence examples for scope of substrates from inspiring English sources

The mechanism of the conversion has been proposed, and the reaction exhibits scope of substrates.

Excellent yields were obtained for a wide scope of substrates under remarkably mild conditions (water, aerobic conditions, room temperature, catalyst loading as low as 0.15 mol %).

Their objective was thus in line with our goal of expanding the scope of substrates that can be reacted with difluoroalkyl-containing sulfinate reagents.

18 This reaction was applied to the total syntheses of EO9 and murrayaquinone A, 19 but the improved regioselectivity came at the expense of generally low yields and a poor scope of substrates, as evidenced by the wide range of conditions that were employed.

Cathepsin B has a relatively broad scope of substrate, but it preferentially recognizes certain sequences such as phenylalanine-lysine (Phe-Lys) and valine-citrulline (Val-Cit) and cleaves a peptide bond on the C-terminal side of such sequences.

The scope of the substrates was studied and the interpretation of the manifest improvement of the reaction rates and enantio-selectivity of the novel catalyst system was speculated.

These approaches expand the scope of radiofluorination substrates and place the challenge on the ability to synthesize the required precursor molecules.

As a consequence, the use of CuAO-like catalytic systems has emerged in synthetic strategies,[ 4] especially because some biomimetic catalysts may offer advantages over CuAOs for expanding the scope of possible substrates.

Moreover, the inability to efficiently employ mammalian cells and multicellular organisms for evolving tRNA/RS pairs further limits the scope of unnatural substrates available for probing in vivo protein function in organisms more complex than microbial hosts.

A further delineation of the scope of aromatic substrates that participate with catharanthine in the Fe(III -mediated couplIII -mediated the definition of its key strucouplingeatureactionired for partheipation in the reaction, andefinitionnsiof to a generalitsd indole functionalization reaction that bears little structural relationship to catharanthine were defined.

The other BVMOs belonging to this group are both of microbial and fungal origin (Miyamoto et al. [1995]; Jiang et al. [2009]; Qiao et al. [2011]) and are known to be very versatile in terms of their substrate scope, and efficiently catalyze the oxidation of a wide range of substrates, which indicates a broader application potential (Fink et al. [2012]; Bianchi et al. [2013]).