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By using the Pauli decomposition, the scattering matrix S can be transformed into a scattering vector k.
Fig. 4 Measured scattering functions P q) as a function of squared scattering vector q 2 and fits for the determination of radius of gyration for the nanoparticles.
The scattering vector Q is defined as with the scattering angle δ and the wavelength λ.
The scattering vector, which is defined in terms of the scattering angle θ and the wavelength of the radiation λ, is q = 4 π/ λ sin(θ/2).
All SAXS patterns were radially averaged to obtain the scattering intensities, which were dependent on the scattering vector q=4 π/ λsin θ, in which 2 θ is the scattering angle and λ the X-ray wavelength.
The scattering vector along the intermolecular stacking direction decreases from P1 to P5.
The terms q xy and q z denote the component of scattering vector in-plane and out-of-plane with the substrate, respectively.
The reconstructed XRD is a subset of the PDF measurement utilizing the low Q region of the data, where Q is the magnitude of the scattering vector (Q=4πsinθ/λ).
The scattering vector at the scattering maximum in the perpendicular direction qm,⊥ significantly shifted to smaller q, where q represents the magnitude of the scattering vector, when the microphase separation occurred.
The scattering vector dependence of the collective relaxation rates estimated for both fast and slow processes indicated a minimum at scattering vector q = 1.5 Å−1, corresponding to the position of a peak in the static structure factor.
However, no definite scattering peak was observed as a function of scattering vector characterizing the latter stage of spinodal decomposition.
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