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The upper scanning limit had obvious influence on the active sites for the methanol oxidation reaction in the backward scanning stage.
Moreover, in this study the lowest scanning limit of the TRF distribution was fixed at 2 kb, although on some occasions the TRF signal (above background) clearly extended to below 2 kb.
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This fast scanning limits diffusion distance to the electrode and minimizes electrode fouling [ 20, 139, 140].
Four segments of titanium (Ti) wire were inserted into the PEG blocks, a short distance from the tissue, to mark the scanning limits of the XRF instrument.
The data are further clouded because the high costs of scans limit the size of most studies.
These features are examined as a function of hydrogen and proton concentration, anion type and concentration, potential scan limit, and temperature.
We establish rigorous estimates of the error induced by the slow scan limit approximation and discuss in detail how this should influence the choice of experimental parameters.
The effects of double-layer capacitance are generally large under the slow scan limit approximation and can cause difficulties in isolating the higher harmonics due to spectral leakage in the power spectrum of the FFT.
Analytical solutions for the current response of an ac voltammetric experiment on a reversible redox system have traditionally relied on two approximations: the "slow scan limit approximation" and small ac potential amplitudes.
For imaging, the vertical scan limit was reduced to ∼1.5 μm.
Additional scans with adjusted negative scan limit and scan rate were applied to electrochemically determine the surface area according to 41. Electron micrographs of all samples were taken with a Zeiss Supra 60 VP.
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