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The rapid scan spectrometer was used to determine the heterogeneous electron transfer rate parameters for the oxidation of Biliverdin in DMF by single potential step thin layer spectroelectrochemical techniques and yielded an average formal heterogeneous electron transfer rate constant K0′s,h = 2.45 (±0.12) × 10−4 cm s−1, electrochemical transfer coefficient α = 0.694 ± 0.008.
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Raman spectra were carried out at room temperature, using HR UV 800 confocal scanning spectrometer (Horiba Jobin Yvon) equipped with a Peltier-cooled charge-coupled device.
The optical absorption spectrum was measured in the range of 200 to 800 nm using a UV-3101PC UV vis-NIR scanning spectrometer (Shimadzu Corporation, Nakagyo-ku, Kyoto, Japan).
Nielsen et al. (2002) reported a long-term variation in the OH rotational temperature using a 20-year dataset obtained with an Ebert-Fastie scanning spectrometer at Longyearbyen, Norway (78°N).
Raman spectra were recorded at room temperature in the range of 100 800 cm−1 with an HR-UV 800 confocal scanning spectrometer (Horiba Jobin Yvon), equipped with a Peltier-cooled charge-coupled device (1152 × 298 pixels) with spectral resolution of 0.5 cm−1.
The first long-term observation of the OH rotational temperature that showed seasonal and interannual variations was a 7-year study using a Czerny-Turner scanning spectrometer at Davis Station (68.6°S) (Burns et al., 2002).
ESR spectra were recorded after addition of CMH (final concentration 200 μM) under stable temperature conditions using a Bruker e-scan spectrometer (Bruker Biospin).
The EPR measurements were carried out at room temperature using a Bruker Biospin's e-scan spectrometer operating at 86 KHz field modulation.
Samples were removed briefly as needed for spectral analysis.> FT-NIR hyperspectral images were acquired using a Varian/Agilent UMA 600 FTIR microscope, coupled to a Varian/Agilent FTS 7000 rapid-scan spectrometer.
A longer term goal should be a spaceborne Na or Fe lidar to provide much improved vertical and horizontal resolution compared with a limb-scanning spectrometer.
In this paper, we present algorithms for both the integrated 0.8 2.0 nm flux and for specific spectral bands recorded by the scanning spectrometers in the 0.6 2.5 nm range.
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