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RS synthesized the samples and contributed to the data evaluation.
LV performed structural characterization of the samples and contributed to the manuscript writing.
LV performed the laboratory X-ray powder diffraction measurements, made the structural characterization of the samples and contributed to the manuscript writing.
AAA collected the samples and contributed knowledge to the method development; ZX assisted in making the micro-column and procuring the materials.
DWD provided human samples and contributed to critical discussions.
DW collected the samples and contributed to the manuscript.
MG collected samples and contributed to the study design.
MR collected and processed samples and contributed to data analysis.
PW prepared the IgG patient samples and contributed key ideas.
ND provided OA knee samples and contributed to the discussion.
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The assay is currently being used for clinical testing of tumour samples and contributing to cancer patient management.
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