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A further potential advantage of droplet-based sample introduction is a substantial reduction in reagent consumption by utilizing an all-droplet format, i.e., reactions performed in droplets, which could achieve over a 1000-fold reductinn in reagents.
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Automated continuous sample introduction was achieved by scanning the capillary tip through the slots of reservoirs.
Based on the above information, the feasibility of an induction heating arrangement for thermal sample introduction was evaluated, with recommendations being made for the future design of IH-ETV instrumentation.
Detection limits for LA sample introduction were computed as three times the standard deviation for the carrier gas blank divided by the slope of the calibration line established using seven pressed concretion tablets.
These differences in relative sensitivities between the two modes of sample introduction are likely caused by a combination of various processes occurring during ablation, sample transport and in the ICP, as well as during ion extraction and transport through the mass spectrometer.
Sample introduction was done with New Objective Econo12-N uncoated borosilicate glass emitters.
Sample introduction was achieved using a Poiseuille flow capillary system developed in-house.
The flow rate for sample introduction was set to 0.8 mL/min.
The sample introduction channel is pressurized such that when the pneumatic microvalve opens briefly, a variable-volume sample plug is introduced into the loading channel.
If high sample throughput is required, alternative sample introduction methods are therefore necessary.
A novel laboratory-constructed electrostatic precipitator for the determination of analyte transport efficiencies from a tube furnace electrothermal vaporization (ETV) sample introduction system is described.
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