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Fig. 8 High-resolution image of grain boundary for MWS sample consolidated at 1400 °C.
The smallest grain size (d ~ 80 nm) was observed in the MWS sample consolidated at 1400 °C (Fig. 7a).
This is about two times higher as compared to the average grain size of MWS sample consolidated at the same temperature (Fig. 9).
The glassy bulk sample consolidated for 600 s at 923 K had a relative density of 99.2%, a saturation magnetization of 46.6 A m2 kg−1, a Curie temperature of 425 K and a low coercivity of 6 A m−1.
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The increase in pre-reaction results in lower stored energy content for samples consolidated to 400 and 500 °C in comparison to samples consolidated at 25 °C.
Samples consolidated at 300 °C exhibit an abrupt change in temperature response prior to the main ignition temperature.
The 80-nm grain size TiN samples consolidated by MWS at 1400 °C exhibited well-connected grain boundaries.
The smallest grain size (d ~ 80 nm) was recorded in MWS samples consolidated at 1400 °C to the density 94.5 %.
In contrast, the resulting densities of the SG composite are higher than the CA composite for samples consolidated at 400 and 500 °C.
MWS and PS45 samples consolidated at 1500 and 1400 °C, respectively, demonstrated Vickers hardness ~21 22 GPa, which is in a very good agreement with the calculated values.
For samples consolidated at 25 °C, the density of the CA composite is 61.65 ± 1.07% in comparison to 56.41 ± 1.19% for the SG derived composite.
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