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The fiber in SPME analysis can adsorb sample compound from the gas phase in the vial (headspace sampling) or directly from the sample solution (liquid-phase sampling).
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This gives the opportunity to remove unwanted sample compounds from the well.
The mass spectrometer records a set of mass spectra for the sample and each spectrum contains the signals for a subset of the sample compounds eluting from the column at a specific retention time (rt).
Cluster sampling method was then used to sample two compounds from the estate (Mimosa chithando and Mpumula chithando) where the study was conducted.
It is used effectively to provide high-level categorizations for a random sample of compounds from the "Chemical Entities of Biological Interest" (ChEBI) ontology.
Within food monitoring studies, we first examined frequencies of detection as a percentage of positive food samples for each phthalate compound from total samples analyzed.
The values at room temperature obtained for nanocomposites compounded by a modified solvent evaporation method via attrition milling in acetone were similar to those from samples compounded by twin screw extrusion.
The results obtained prove the ability of PTh material as a new fiber for sampling of organic compounds from water samples.
In order to extract the volatile compound from the samples, a DVB/carboxen/PDMS stable flex (50/30 μm) (Supelco Co., Bellefonte, PA, USA) SPME fiber was used.
As a sensitive and rapid method for determination and identification of chemical compound from complex samples, high performance liquid chromatography tandem mass spectrometry (HPLC MS) has been used as a powerful method for β-lactam antibiotics determination [ 15].
A sphere exclusion (SE) algorithm was utilized to randomly sample 'presumed inactive' compounds from a pool of ChEMBL compounds using a dissimilarity radius from known actives.
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