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The phenyl phenyl correlation in the freeze-dried a-PS is weak compared with that in the reference sample cast from a 5 wt% solution in tetrahydrofuran.
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This order holds both for amorphous solid samples and samples cast from N-methylpyrrolidone (NMP) solution.
Samples cast from 20 wt% solutions in dimethyl acetamide were utilized.
The temperature of the maximum rate of cure in the dynamic mass spectroscopy data decreased with increasing solvent content and the temperature range over which imidization occurred narrowed by 300% for samples cast from NMP solution compared with solid samples precipitated from solution.
However, no significant difference in scaffold thickness was observed between samples cast from 5 and 30 min degummed silk at different time points.
The model film samples casted from the initial components were treated and studied as well.
When the sample was cast from chloroform solution and annealed at 150 °C, a double gyroid (DG) phase was obtained.
The FTIR-Raman spectra of polydiacetylenes with chiral pendent groups (–(CH2)nOCONHC*H(CH3 Ph; n=2,3,4,6 and 9; nR(S MBU) were measured for samples as polymerised, cast from solution and precipitated on filter paper.
The Raman spectra of SWNT PVP and SWNT:agaroza samples exhibit similar changes as the SWNT DNA samples when films are cast from the corresponding solutions.
Higher-order peaks arising from the ordered lamellar stacking of PEG (i.e. the lattice peaks) were observed in the various blend samples, as well as in the PEG 100% sample, all of which were cast from their solutions in dichloromethane.
It should be noted that the T1C values of the crystalline and noncrystalline components are appreciably smaller for the melt-crystallized films than those for the un-annealed and annealed samples prepared by casting from the aqueous solution.
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CEO of Professional Science Editing for Scientists @ prosciediting.com