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Bulging can be recognized at the lateral sample boundaries.
a BSE image of a polished surface around the upper and lower sample boundaries.
The upper and lower sample boundaries are shown as white dashed lines.
However, nucleation rate in the grain boundaries and sample boundaries is higher than that of other sites.
IR spectra from the upper and lower sample boundaries show that water is dominantly trapped within the zoisite (Fig. 9).
Fig. 9 IR mapping results for the upper and lower sample boundaries of the water-added experiment.
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The sample boundary is shown as a white dashed line.
c, d Secondary electron images of broken surfaces within approximately 200 μm of the sample boundary.
c Sample boundary and upward fracture (cross-polarized light with a gypsum plate).
Unlike the results for the sample boundary, the mapped area did not show a concentration gradient of water.
The bulging and reduction of pores in the water-added sample indicate that plastic deformation and the anorthite water reaction were concentrated around the sample boundary.
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