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These two effects were related to the scattering of photoexcitation beam in the sample and reference materials.
The most important factor determining the precision was demonstrated to be higher sample and reference material weights.
It is shown that experimental design (sample and reference arrangements) has a significant impact upon the derived data.
Light emitting diode (LED) arrays were used to illuminate the sample and reference channels of the calorimeter.
These CO2-sensing properties were largely dependent on humidity in sample and reference gases and CO2 concentration in the reference gas.
A thorough investigation of calibration techniques showed that the calorimetric performance is very sensitive to the thermal conductivities of the sample and reference fluids.
Both the sample and reference are maintained at the same temperature throughout the experiment.
The empty sample and reference pans were taken of equal mass for analysis.
These were put into the sample and reference holes until both rest on the base of the holes.
The temperature of the chamber is then suddenly changed, and the temperature response of sample and reference is recorded.
The spectra backgrounds were recorded with both sample and reference cuvettes containing the matrix used to make up the sample.
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