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Exact(5)
However, this resolution is not sufficient to resolve Λ-splitting effects for each rotational line.
The N2 1PG (4-4) band emission partially overlaps a rotational line of the OH (8-4) band.
Concentrations were determined using a combination of singular value decomposition matrix techniques and fitting of rotational line sequences.
The rotational line P1(4) is not used for temperature derivation because there is a strong water vapor absorption line near it.
Fig. 22 Rotational line profile of Aniline 0 0 origin in helium gas jet with estimated temperature from spectral calculation [61] Fig. 23 Spectra of helium clusters on Anthracene indicating the low temperatures achieved (less than 0.8 K) [21].
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The characteristic spectral structure of HCN molecules was identified in the rotational line-resolved IRPS spectra collected in flames at around 3248 cm−1.
The intensities of rotational lines P1(2), P1(3), and P1 5) are used to derive the rotational temperature.
No splittings of the rotational lines due to the ring puckering of the cyclopentane ring have been observed.
The intensity ratio between two rotational lines can be converted to the rotational temperature, which is equivalent to the atmospheric temperature, by assuming a local thermal equilibrium.
Consequently, two rotational temperatures were derived from two pairs of rotational lines, i.e. P1(2)/P1(5) and P1(3)/P1(5), to remove data affected by auroral contamination.
Since the spectral intervals of the rotational lines in the OH (8-4) bare are larger than 1.7 nm, the resolution is sufficient to resolve these lines.
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