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The internal molecular rearrangements during relaxation are identified and accounted for by the rotation of specific atomic groups.
Calculations of relative bond flexibility and the energy barrier for bond rotation of specific moieties in the minimized energy chain conformation correlate with molecular mobility as measured by sub-Tg transition temperatures.
A factor analysis (principal component extraction with varimax rotation) of specific items revealed three factors (Eigenvalues > 1.7) explaining 75.6% of the total variance; namely Side effects (4 items, 28.4%, Cronbach's Alpha =.87), Effectiveness (3 items, 24.1%, Cronbach's Alpha =.85), and Convenience (3 items, 23.1%, Cronbach's Alpha =.87).
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Additionally it is theoretically and experimentally demonstrated that polarization state of terahertz pulse changes with the rotation of sample at specific frequency.
A first EFA employed principal components extraction and a subsequent orthogonal varimax rotation of the more specific TS-M items.
For its absolute configuration, it was hardly to identify the configuration of 7 ( − 6.7, c 0.14, MeOH) by comparison with the values of specific rotation of orthosporin dimethyl ether ( +18.9, c 0.03, MeOH) on account of the values of specific rotation was too small to discriminate whether it was experimental error or not [15].
The resulting polymers are optically active, but show a nonlinear dependence of specific rotation vs. incorporation of chiral monomer.
The sign of specific rotation is indicated in brackets and was assigned according to the literature for reference biotransformations.
X-Ray crystallographic studies suggest that inversion of the propeller configuration of the coordinated PPh3 ligand is a major contributor to the switch of specific rotation.
The resulting polymers are optically active and display a variety of non-linear dependencies of specific rotation against %-chiral monomer incorporation.
The polymers contain acid labile protecting groups that can be removed to generate a second series of polymers, which also show non-linear dependencies of specific rotation against %-chiral monomer incorporation.
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