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However, recent studies have shown that their presence regulates the sterol ring tilt angle in the bilayer [23], [29], and the interaction with double bonds of neighboring lipid acyl chains [21], [22].
The same basic coordination is observed, though the ring tilt is smaller because of the alanine occupying position 95.
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The tail of the α-heavy chain, identified by analyzing the oda11 mutant, which lacks α-heavy chain, extends from the AAA ring tilted toward the tip of the axoneme and towards the inside of the axoneme at 50°, suggesting a three-dimensional power stroke.
The exterior rings tilt at 30° in the same sense and thus form helical structures with P and M geometries.
In the case of D3, though β6 β7 is the most persistent at 500 K, β7 β8 is also persistent at 600 K. Residues F222 and Y229 in β6 β7 form favorable interaction with their side-chain aromatic rings tilted at a mean angle of 57° (from control simulation).
The ability of the sugar ring to tilt in subsite −1 is potentially relevant to the conformational requirements of an α-retaining mechanism.
Shielding of H5′ and H4′ protons upon metal ligand bond formation may have occurred due to ring current effects or steric effects of the phenyl rings which tilt the N-Re N plaN-Re Nn N coordination to Re.
The central phenyl ring is tilted at 44° with respect to the pyridyl rings and results in a chain of CH···π interactions through the ester and the central phenyl rings, highlighted in red in Figure 6c.
In contrast, on Zn-modified Pt(111) surfaces, guaiacol was found to bond to surface Zn sites via the oxygen atoms in the molecule producing a bonding configuration in which the aromatic ring is tilted away from the surface.
33 The uncoordinated phenyl ring is tilted by 41.06° relative to the main plane defined by the coordinated ph(bound).
The central phenyl rings are tilted at 26° and 36° with respect to the pyridyl rings for the two half-molecules, which is less than for those in 5.
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