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Variations in the strain maps in the zone affected by shear and tensile stresses are analyzed, and the difference in response between specimens is pointed out, particularly with respect to ring orientations.
Specifically, we measured the complementarity in terms of the pseudocenter proximity, charge complementarity, surface fit as well as aromatic ring orientations (favoring perpendicular and parallel π stacking).
Similar(58)
Linker dependent reactivity patterns are related to azole ring orientation effects and some aspects of cyclometalation are considered.
In contrast, the extent of benzene ring orientation parallel to the bottle surface showed little variation and remained consistently high at the majority of the surface bottle positions probed.
The ring orientation observed in YbdB allows hydrogen bond formation between the ring C(2 OH and the His54, whereas the ring orientation observed in YdiI allows hydrogen bond formation between the ring C(2 OH and the Asn48.
Another important change is the leucine to glycine modification at position 105, which allows chlorophyll 3005 to alter its ring orientation by approximately 12°.
This is most likely because the extra methyl group on the pyridine in (3 R,4 R) - 3 imposes additional restraints on the ring orientation via its van der Waals contact with the Phe584 side chain.
As a consequence of the elbow-like rotation of the methylene phosphate PLP tail in the mutant T254 forms, the PLP ring orientation also diverges from that of the wild type.
Arguing for the lack of temporal coordination between actomyosin contractility and activation of septum assembly, inhibition of septum deposition allows mid1Δ cells sufficient time to correct ring orientation [ 11].
The similar populations for the minor conformers of Trp and Glu in this crystal structure is consistent with a concerted shift for both the indole ring orientation and the backbone hydrogen-bonding geometry for residues 59 and 60, which, in turn, appears to be at least partially coupled to a reorientation of the Glu side chain.
The pentafluorophenyl rings adopt orientations where an N atom of a diethylamino group is coplanar to the ring [N P C C smaller than 1.8(2)°].
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com