Exact(8)
The biphasic medium does not require rigorous stirring.
Following this, 0.6 M thiourea solution was slowly added to the mixture with rigorous stirring.
In a typical procedure, 0.1 ml aqueous of 0.05 M HAuCl4 was added into 5 ml rGO SDS aqueous dispersion in a 10-ml bottle under rigorous stirring for 1 h.
One hundred eighty milligrams of silver nitrate was mixed with 100 ml of deionized water under rigorous stirring in a nitrogen atmosphere created by high-purity nitrogen passed into the solution, which was maintained during the reaction.
For a synchronous addition, 10 mL of solutions A and B was simultaneously and stoichiometrically added to a reactor pre-filled with 20 mL of anhydrous ethanol using a syringe pump (model: KDS 270, KD Scientific Inc., Holliston, MA, USA) at a feeding rate of 2 mL·h−1 under rigorous stirring at RT.
After purging with high-purity nitrogen for half an hour, the valves and inlet were closed, and the reactor was immersed into a thermostatic oil bath at 110 and 65 °C for styrene (St) and methyl methacrylate (MMA) polymerization, respectively, under rigorous stirring.
The non-synchronous feeding was carried out in a non-stoichiometric way, where 1.0 mL of solution B was transferred to a reactor and the remaining 9 mL of solution B and 10 mL of solution A were then fed synchronously (1 mL·h−1) into the reactor under rigorous stirring at RT.
This solution was filtered using a PTFE filter membrane (0.45 μm pore size) to form cloudy solution B. Then, solutions A and B were mixed either in a simple way by pouring B into A within 1 s or in a slow way by feeding B into A using a syringe pump within 1 h (non-synchronous) under rigorous stirring at room temperature (RT).
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