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In most extant bryozoans the zooids are not cylindrical but flat, with rigid side walls.
This model is believed to be applicable for polymers with short and rigid side chromophores active for the SFG spectroscopy.
With regard to the quality of fracture reduction, uniplanar devices with a rigid side bar are usually more difficult to adjust and the surgeon must take care to ensure a satisfactory reduction before the external fixator is applied.
The pretilt angles of the liquid crystal on the polyimide (5a) with rigid side group was 0.6°, on the other hand, the pretilt angle on the polyimide (5b) and (5c) with flexible side chains were very high above 89.6°.
These results indicate that proton transport in low water content S-SEBS occurs via a thermally activated process (ion motion via energy barriers) that is consistent with the more rigid side chains in that material.
This may be explained by the inherent stability of the device we used (a rigid side bar), allowing for dynamization of the fracture, the operative technique, adherence to basic surgical principles and an effort to achieve an anatomical reduction including axial and side-to-side compression.
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Here, we use a coarse-grained model to study an end-linked flexible polymer network diluted with branched polymer solvent chains, where the latter chains are composed of rigid side-chains or "spikes" attached to a flexible backbone.
In order to reduce the entropy penalty of the flexible polymer chains these rigid "spikes" will aggregate into clusters, but the extent of aggregation was shown to depend on the size and distribution of the rigid side-chains.
The model is applied to single-foundation noise barriers to which additional absorbent or rigid side-panels are added to create profiles and a double-barrier configuration is also studied.
All these results show that the copolymers containing H at the α-position and flexible side-chain in comonomer have lower surface free energy and higher surface reorganization, while the steric hindrance effects of α-methyl groups and/or rigid side-chain in comonomer allow the copolymers having higher surface free energy and lower surface reorganization.
A series of mesogen-jacketed liquid crystalline polymers (MJLCPs) with polynorbornene as the main chain and cholesteryl mesogenic units at the ends of the side chain, PNbnChol (n = 1, 3, 5, which is the number of benzene rings in the rigid side-chain core), were prepared by ring-opening metathesis polymerization.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com