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Wide angle X-ray diffractograms (WAXD), positron annihilation lifetime spectroscopy (PALS) and molecular dynamics simulations reveal that the excellent barrier properties of 2,7-CPPI are mainly ascribed to the crystallinity, high chain rigidity and low free volume, which are resulted from the rigid planar structure and strong hydrogen bonding among molecular chains.
The results revealed that the core structure is required for activity and it should be aromatic, rigid, planar, symmetrical and conjugated for optimal activity.
Furan polyamides displayed higher van der Waals cohesive energy densities and maintained more rigid planar structures near furan rings compared to nylons.
A plane sound wave is obliquely incident on a semi-infinite elastic cylindrical shell (tube) which is mounted perpendicular to a rigid planar baffle.
A two-dimensional thin-walled capsule of a flexible permeable membrane is adhered onto a rigid planar substrate under adhesive forces (derived from a potential function).
As a rigid, planar and electroactive species, MB can intercalate inside the regular self-assembled monolayers (SAMs) of n-hexanethiol and exhibit well-defined electrochemical responses.
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Hence, CVD polymers can be readily applied to virtually any substrate: organic, inorganic, rigid, flexible, planar, three-dimensional, dense, or porous.
This is promoted by their multifunctionality, biocompatibility, flexible and tunable molecular structure by chemical modification, rigid and planar molecular skeleton, which make porphyrin-involved nanomaterials have rich assembly, physicochemical and biochemical properties [26, 27, 29, 32 39].
In contrast, films with rigid and planar molecular structure show CTE increase according to the increase of film thickness up to 40 50 μm, which then plateau for thicker films.
As a rigid and planar aza-based heteroaromatic scaffold, hexaazatriphenylene (HAT) exhibits excellent electron-deficient property and high π-π stacking tendency, which makes it an ideal building block in the construction of supramolecular architectures and functional materials.
Although wafer based electronics are known to be rigid and planar, recent advances in manufacture and mechanics have made intrinsically stiff and brittle inorganic electronic materials stretchable and compliant.
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