Sentence examples for retention shift from inspiring English sources

The mean value of retention shift is set to follow the mean of sum of interface traps and oxide traps: μ d = ( A t · N a IT + B t · N a OT ) · ln ( 1 + t ).

As for retention shift, we set σ d  = 0.3|μ d |, and A t  = 3.5×10−5, B t  = 2.35×10−4, which are chosen to match the 70%30%% ratio of interface trap recovery and electron detrapping presented in [12].

Deuterated analogs have no observable differences in their chromatographic retention approximately up to six deuterium atoms [ 157], but a very small retention shift can occur for higher deuterium numbers, as illustrated for the example of d9 1-hydroxypyrene [ 168].

MAPK14-intron 2 retention shifts the reading frame and disrupts a kinase domain in the protein product.

Unfortunately, deuterium may result in retention shifts in chromatography, and Δ m between glycan pairs for these labels is only 4 Da.

However, when using on-column injection, care must be employed to ensure a clean sample, to prevent coextracted compounds from building up in the retention gap and column leading to increased noise, peak tailing, retention shifts and reduced lifetimes of the columns.

With use of this approach, a difference of 6 Da is generated between the two different glycans, which is sufficient to have full resolution of the isotopic patterns of glycan pairs in MS. Moreover, the use of deuterium is avoided, so no retention shifts on C18 columns are observed.

To correct for retention time shift, here, we adopted "on-the-fly" recalibration of retention time shift with spiked-in reference peptides in the targeted kinome analysis.

However, the use of 100% aqueous solution (as HPLC mobile phase) may collapse the C-18 bonded phase and result in a retention time shift.

In one case we observed a retention time shift.

Thus, without the on-the-fly correction of retention time shift, the transitions of these two peptides would not be captured in the predicted retention time window.