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Tribolium castaneum was used as a retention database.
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For building a reliable retention time database or even predicting retention times for other FAHFAs, a larger range of authentic reference standards would be needed.
The criteria for identification were over 80% confidence match from the mass spectra library and a match to the retention time database within 5 seconds of relative retention together with a manual check of the retrieved mass spectrogram against the library mass spectrogram.
Korytár et al. [ 29] recently published a retention time database for 126 PBDE congeners using seven different capillary columns with varying film thicknesses (Table 2).
Few retention factor databases have been developed for food nutrients; the United States Department of Agriculture USDAA) Table of Nutrient Retention Factors (13) and Bognar's tables on retention factors of food constituents (14) contain data on vitamins, minerals and other micronutrients, but not polyphenols.
With ToxID, analyte detection was done fully automated by the software and based on the presence of the exact mass (±5 ppm) in a scan within a given time window (the database retention time, ±30 s).
Analyte detection was based on extraction of the exact mass (±5 ppm) of the major adduct ion at the database retention time ±30 s and the presence of a second diagnostic ion.
This should be followed with a global profiling paradigm, first aimed at getting the best possible exact MS data, in particular with retention time locked databases, subsequently re-run to obtain MS/MS to aid database searching.
Before charges are laid he is fingerprinted, photographed and required to provide a sample of his DNA for indefinite retention by the police database.
A database of retention basins with flood control potential has been developed for Scotland.
The database contains retention time indexes from compounds which were identified in indoor air samples at NILU on exact the same analytical system over the last 20 years.
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