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The two subunits of the prepared bis-Schiff bases predominantly retain in solution the same tautomeric forms as found in the solid state.
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The obtained supernatant was filtered through a coarse filter to obtain microspheres retained in solution.
The U IV) was retained in solution in these experiments, most likely by complexation with citrate present in the experimental medium.
This cluster type, which is also retained in solution, therefore appears to be very robust.
5 The approximate C2 symmetry is retained in solution because only one signal was observed in the P NMR spectrum.
Our residual dipolar coupling and N relaxation NMR data indicate that HscB retains in solution the fold and associated dynamics observed in the crystal.
The backbone H4/H5 protons are also shifted to low frequency from 7.53 ppm in [EMIM]I to 7.39 ppm in [EMIM][GeI3], confirming that only very weak interactions were retained in solution.
After treating the [F]FPBZA-added serum with acetonitrile followed by centrifugation, only a small portion of radioactivity was found in the serum protein precipitate and >90% of the radioactive components retained in solution.
As the chiral configuration of each enantiopure ligand is retained in solution, the OsII arene complexes were obtained as a mixture of two diastereomers differing only in the metal configuration (ROs or SOs).
The geometry and resultant asymmetry of compound 1 in the solid state is, therefore, suggested to be reflective of the lowest energy conformer and is not retained in solution.
All these data are consistent with η-coordination of the amine borane being retained in solution.[ 17, 19] Complex 4 can also be formed by reaction of 5 with Na[H3BNMe2BH3], revealing that the xantphos′ ligand can adopt a flexible coordination mode[ 20] in response to the requirements of the amine borane ligands.
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