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The influence of the degree of photoreaction and the annealing temperature on the thermally enhanced molecular reorientation behavior was explored in detail.
This paper describes the synthesis and influence of the substituent on the reorientation behavior of photocrosslinkable methacrylate polymer liquid crystals (PPLCs), which contain p-substituted cinnamoyloxybiphenyl (CB) side groups.
Such reorientation behavior exhibited dependence on the correlation between the crystallization temperature (Tc), the glass transition temperature of PS (TgPS), the peak melting point of PLLA crystals (TmPLLA), and the end melting point of PLLA crystals (Tm,endPLLA).
Liquid crystalline (LC) and non-LC copolymers that contain 4-methoxyazobenzene side groups and methyl methacrylate units were synthesized to compare the photoinduced reorientation behavior using the polarization absorption spectra of thin films.
For the diblock copolymers, the reorientation behavior was analogous to the methacrylate homopolymer with MCB side groups and transmission electron microscopy revealed a phase separation structure with molecular orientation of the MCB groups.
First, the consideration of local grain neighborhood has a significant influence on the reorientation of a grain (up to 20% in terms of its end orientation and its orientation density), but its own initial orientation is more important for its reorientation behavior than its grain neighborhood.
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The photoinduced reorientation behaviors of liquid crystalline (co polymethacrylates (LCPs) comprised of N-benzylideneaniline (NBA) and 4-cyanobiphenyl or 4-methoxybiphenyl side groups are compared using linearly polarized (LP) 313 nm and LP 365 nm light.
These authors propose the existence of background reorientation mechanisms (i.e., a fractal reorientation clocks) which generates Lévy intermittence, efficiently alternating scanning and reorientation behaviour.
The behavior of reorientation of liquid crystal molecule forms a phase grating which makes the incident angle steer to the angle as we desire, so as to a nonmechanical laser beam steering.
This work uses the microsphere-based approach to take into account the micro mechanics involved in biological fibered structures regarding both their passive behavior and the reorientation of their micro constituents.
The model is able to describe all the behaviors of martensite reorientation in FSMA observed in the existing experiments: rotating/non-rotating magnetic-field-induced martensite reorientation, magnetic-field-assisted super-elasticity, super-elasticity under biaxial compressions and temperature-dependence of martensite reorientation.
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