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Moreover, the unique ordered hierarchical architecture could greatly relieve the volume change and stack during the electrochemical process, resulting in the excellent cycling stability.
It is believed that the S-doped carbon matrix acts as an effective buffer layer helping relieve the volume strain as well as a hinder preventing FeS2 from aggregating during cycling, which ensure the high electrochemical performance.
Such superior electrochemical performance can be attributed to the unique multiple structure, which cannot only effectively shorten the transport path of Li+ ions and enhance the conductivity, but also relieve the volume change and prevent agglomeration of Mn grains during the phase transformation in the conversion reaction.
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This structure provides shortened paths for Li+ diffusion and freeways for electron transfer, moreover, it effectively relieves the volume change of MoC nanocrystallites during the discharge/charge cycles.
Furthermore, the hierarchical microflower-like structure prevents aggregation of MoS2 nanosheets, while the sandwich structure relieves the volume expansion and dissolution of PANI during repeated charge/discharge cycles.
The 3D composite network provides a new design principle of robust and scalable lithium-ion battery electrodes that can effectively relieve the significant volume change problem.
Such a hierarchical multi-shell structure can not only amplify active mass-electrolyte contact area and minimizes lithium ion diffusion path, but also provides a unique interstitial void space to relieve the huge volume change of material.
Moreover, the inactive materials, such as the oxide in the superficial layer and the Cu in the bottom layer, could also act as buffers to relieve the induced volume expansion of Sn during the repeated lithiathion/delithiation process, thus giving the good cycle performances.
The densely stacked spherical nanoparticles can efficiently relieve the decrease of volume energy density [135].
Work resumed west of Highway 24 during the spring of 1982 to connect with Highway 401 near Woodstock in order to relieve the high traffic volumes along Highway 2.
Thirdly, the hollow structure could effectively relieve the structural strain and volume change which can be much more helpful for its long-term circulation.
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